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Synthetic, Protecting & Derivatization Reagents

Trimethyl silyl triflate, 99%

PurissAvailable on request

Order Trimethyl silyl triflate, 99% (CAS 27607-77-8) online at Zemixal. Lab and bulk packs, batch COA, fast global delivery.

Pack sizes
Trimethyl silyl triflate, 99% chemical structure
CAS number27607-77-8
FormulaC4H9F3O3SSi
Molar mass222.26 g/mol
Physical formLiquid
HS code29319090
UN numberUN 1993
Purity99%
InChIKeyFTVLMFQEYACZNP-UHFFFAOYSA-N
IUPAC nametrimethylsilyl trifluoromethanesulfonate

About Trimethyl silyl triflate, 99%

Zemixal supplies Trimethyl silyl triflate, 99% within its laboratory Chemicals & Reagents portfolio. Key data (Puriss): CAS 27607-77-8, formula C4H9F3O3SSi and molar mass 222.26 g/mol. Typical appearance is colorless to light yellow to light orange liquid.

Typical applications

  • Organic synthesis
  • Reaction development
  • Medicinal chemistry
  • Catalysis

Handling and storage

Reported physical data: boiling point 77 °C and density 1.228 g/mL at 25 °C. It carries the GHS signal word Danger (H226 and H314), so wear gloves and eye protection and work with good ventilation. For transport it ships as UN UN 1993.

Standard pack sizes are 25 g, 100 g, 500 g, 5 x 1 kg and 25 kg, and custom quantities are quoted on request. Each lot travels with a batch certificate of analysis and a 16-section SDS. Send an enquiry through the quote panel and you get a formal offer with Incoterms and delivery time.

Typical uses

  • Organic synthesis
  • Reaction development
  • Medicinal chemistry
  • Catalysis

Applications

Specifications and identifiers

Specifications of Trimethyl silyl triflate, 99%
Product nameTrimethyl silyl triflate, 99%
Catalogue numberZX-001024
CAS number27607-77-8
IUPAC nametrimethylsilyl trifluoromethanesulfonate
Molecular formulaC4H9F3O3SSi
Molar mass222.26 g/mol
Exact mass221.9994
GradePuriss
Purity / assay99%
Physical formLiquid
AppearanceColorless to light yellow to light orange liquid
Boiling point77 °C
Density1.228 g/mL at 25 °C
H-bond donors / acceptors0 / 6
Topological polar surface area51.8 Ų
HS code29319090
UN numberUN 1993
InChIKeyFTVLMFQEYACZNP-UHFFFAOYSA-N
SMILESC[Si](C)(C)OS(=O)(=O)C(F)(F)F
PubChem CID65367
SynonymsTMS triflate, TMSOTf, Trifluoromethanesulfonic acid trimethylsilylester, Trimethylsilyl triflate, Trimethylsilyl trifluoromethanesulphonate, Trimethylsilyl trifluoromethylsulfonate, Methanesulfonic acid, trifluoro-, trimethylsilyl ester, trimethylsilyltriflate, trimethylsilanol trifluoromethanesulfonate, trimethylsilyltrifluoromethane sulfonate, 1,1,1-Trifluoromethanesulfonic acid trimethylsilyl ester, Trifluoromethanesulfonic acid trimethylsilyl ester

Lot values are stated on the batch certificate of analysis. Ask for a typical COA with your quotation.

Safety and GHS hazards

GHS02 Flammable
Flammable
GHS05 Corrosive
Corrosive

Signal word Danger

  • H226Flammable liquid and vapor
  • H314Causes severe skin burns and eye damage

Precautionary statements P210, P233, P240, P241, P242, P243, P260, P264, P280, P301 + P330 + P331, P302 + P361 + P354, P303 + P361 + P353, P304 + P340, P305 + P354 + P338, P316, P321, P363, P370 + P378, P403 + P235, P405, P501

Classification summarised from public GHS notifications. It can vary with grade and concentration, so always follow the SDS supplied with your lot.

Pack sizes

Pack sizes of Trimethyl silyl triflate, 99%
25 gQuoted on request
100 gQuoted on request
500 gQuoted on request
5 x 1 kgQuoted on request
25 kgQuoted on request

Need a different size? Bulk drums and custom packing are quoted on request through the quote form on this page.

Questions about Trimethyl silyl triflate, 99%

Which CAS number identifies Trimethyl silyl triflate, 99%?
Trimethyl silyl triflate, 99% is registered under CAS 27607-77-8. You may also see it listed as TMS triflate, TMSOTf, Trifluoromethanesulfonic acid trimethylsilylester. Our catalogue number for this item is ZX-001024.
What are the formula and molar mass of Trimethyl silyl triflate, 99%?
For Trimethyl silyl triflate, 99%, its formula is C4H9F3O3SSi and its molar mass is 222.26 g/mol. The systematic (IUPAC) name is trimethylsilyl trifluoromethanesulfonate. InChIKey FTVLMFQEYACZNP-UHFFFAOYSA-N lets you match it in any structure database.
What grade and pack sizes are available for Trimethyl silyl triflate, 99%?
This listing is Puriss grade with 99% purity. Standard packs are 25 g, 100 g, 500 g, 5 x 1 kg, 25 kg. Larger quantities and custom packing can be quoted on request.
Which documents come with Trimethyl silyl triflate, 99%?
Each lot ships with a batch certificate of analysis and a 16-section GHS safety data sheet. A typical COA or specification sheet can be shared with the quotation before you order.
Can Zemixal ship Trimethyl silyl triflate, 99% to my country?
Yes. Because Trimethyl silyl triflate, 99% is classed as hazardous (UN 1993), it travels in UN-approved packaging as dangerous goods under IATA or IMDG rules, with the export paperwork your broker needs.

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