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Organic Building Blocks

Hydrocarbons (Alkanes, Alkenes & Arenes)

Alkanes, alkenes, alkynes, substituted benzenes and natural terpenes for synthesis, reference standards, materials and fragrance research.
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GridList
1-Butene
CAS
106-98-9
Formula
C4H8
MW
56.11 g/mol
ZX-034829

Hydrocarbons are often thought of as solvents, but many are valuable building blocks and reference compounds in their own right. This sub-category covers substituted arenes, cyclic dienes, alkynes and sesquiterpenes. Examples include 1,2,3,4,5-Pentamethylcyclopentadiene, the precursor to Cp* metal complexes, 1,3,5-Triphenylbenzene, 1,4-Bis(phenylethynyl)benzene for molecular electronics, 1,3,5-Triisopropylbenzene and natural terpenes such as (−)-Germacrene D and (+)-δ-Cadinene.

Buyers focus on isomer purity, since alkyl benzenes and terpenes often come as mixtures of positional or stereo isomers. Dienes and terpenes can oxidise or dimerise in storage, and some are supplied stabilised. For materials work, rigid aromatic hydrocarbons are chosen for their shape, conjugation and thermal stability, while terpenes are used as GC reference markers in essential oil and flavour analysis.

Products ship in sealed bottles, under nitrogen where oxidation is a risk. Each lot comes with a COA and SDS. Most items are offered in gram quantities, with larger packs for common aromatics on request. Search by formula to compare isomers across the range quickly.

Hydrocarbons (Alkanes, Alkenes & Arenes): questions buyers ask

What is pentamethylcyclopentadiene used for?
Pentamethylcyclopentadiene is deprotonated to give the Cp* ligand, a bulky, electron-rich ring used in organometallic chemistry. Cp* complexes of rhodium, iridium, ruthenium and titanium are important catalysts for C-H activation, transfer hydrogenation and polymerisation. The diene should be stored cold under inert gas to limit dimerisation.
Why are terpenes like germacrene D sold in modest purity?
Many sesquiterpenes are isolated from natural sources or made by routes that give close isomers. They also rearrange easily under heat and acid. Purities around 90% to 95% are common and adequate for use as GC markers or biological tests. Check the COA for the major impurities present.
How should conjugated aromatic hydrocarbons be stored?
Most rigid aromatic hydrocarbons are stable solids that keep well in sealed containers at room temperature, away from light. Alkyne-containing compounds can slowly oxidise or polymerise, so store them cool and dark. For electronics work, keep them away from moisture and contamination that can affect film quality.

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